A model of long-term oxidation and leaching processes in pyritic coal

Pyrite was extracted from the coal using HNO 3 acid. Indeed, the sulfur in the pyritic phase (total reduced inorganic pyrite) was separated from the others. Moreover, an AA-670 Shimadzu atomic absorption system was employed to measure iron in the solution, and then used to determine the fraction of pyrite remaining in each sample. ...

Pyrite, Coal, Kentucky Geological Survey, University of …

Pyrite (FeS 2) is a mineral of particular importance in several coal markets. Sulfur from pyrite can have a detrimental influence on many chemical processes …

Deep abiotic weathering of pyrite | Science

Pyrite is a ubiquitous iron sulfide mineral that is oxidized by trace oxygen. The mineral has been largely absent from global sediments since the rise in oxygen concentration in Earth's early atmosphere. We analyzed weathering in shale, the most common rock exposed at Earth's surface, with chemical and microscopic analysis.

USGS Fact Sheet 073-02: Coal Extraction -- Environmental …

Kinetics of Pyrite Oxidation The acidity of coal-mine drainage is caused primarily by the oxidation of the mineral pyrite (FeS 2), which is found in coal, coal overburden, and mine waste piles.Pyrite oxidation and the consequent generation of sulfuric acid have long been recognized as major contributors to acid rock drainage, yet pyrite reactivity remains …

Thermal decomposition and oxidation of pyrite with different

Pyrite is common in coal gangue formed in a reduced environment and has a significant influence on the recycling utilization of coal gangue. Four types of pyrite with different structures and morphologies, namely octahedral pyrite framboid, pentagonal dodecahedral pyrite framboid, irregular grain pyrite, and euhedral octahedral crystalline …

Role of pyrite in formation of hydroxyl radicals in coal: possible

The harmful effects from inhalation of coal dust are well-documented. The prevalence of lung disease varies by mining region and may, in part, be related to regional differences in the bioavailable iron content of the coal. Pyrite (FeS2), a common inorganic component in coal, has been shown to spontaneously form reactive oxygen species …

Pyrite Suns For Sale

Pyrite suns or pyrite dollars are a unusual pyrite formation exhibiting striations radiating out from the center like rays of the sun. They are found in narrow, compacted seams of slate interbedded in the 300 million year old coal deposits near Sparta, Illinois. People used to believe that pyrite suns were fossils which had undergone pyrite ...

Occurrence Characteristics of Fine-Grained Pyrite in …

Pyrite is the main carrier of the sulfur element in Chinese coal seams. 5, 6 Therefore, identifying the distribution characteristics of pyrite in coal is a prerequisite for …

Pyrite | Properties & Facts | Britannica

pyrite, also called iron pyrite or fool's gold, a naturally occurring iron disulfide mineral.The name comes from the Greek word pyr, "fire," because pyrite emits sparks when struck by metal.Pyrite is called …

Reductive dissolution of pyrite by methanogenic archaea

Pyrite (FeS 2) is the most abundant sulfide mineral in Earth's crust and its formation and fate are key controls on the biogeochemical cycles of iron (Fe), sulfur (S), carbon, and oxygen (O 2

Sulfide Minerals

Pyrite "dollars" with a radiating habit are often found for sale at rock shows. They are nodules of pyrite crystals that grew between layers of shale or coal. Pyrite also readily forms crystals, either cubic or the 12-sided forms called pyritohedrons. And blocky pyrite crystals are commonly found in slate and phyllite.

Control of different pyrite forms on desulfurization of coal with

The formation of framboidal pyrite in coal and sediments depends on the use of organic oxysulfur compounds in dissimilatory respiration by sulfur-reducing bacteria [5].Four processes are involved in pyrite framboid formation viz. – (i) nucleation and growth of initial iron monosulfide microcrystals, (ii) reaction of microcrystals to greigite (Fe 3 S …

Electrostatic Separation of Pyrite From Coal

The electrostatic separation of pyrite from coal using corona roll separator was conducted on Moira Pottery coal, UK, at various atmospheric conditions, various feed pretreatment, particle size ...

Pyrite Suns | The Story of Illinois

These round disks sometimes occur between seams of coal and may be found when coal is mined. Although pyrite is quite common worldwide, the disk form is virtually unique to Illinois. Sulfur, which can occur in coal …

Where to Find Pyrite: Best Environments & Locations in USA

Pyrite occurs in all types of rocks, sedimentary, igneous, metamorphic, or thermal veins. Some of the best environments to find pyrite are mines, hills, mountains, washes and draws, valleys, quarries, limestone deposits, road cuts, granite deposits, clay exposures, or creeks, among many other places. Let's explore some of these …

Removal of pyrite from coal by dry separation methods. Report of

@article{osti_4341578, title = {Removal of pyrite from coal by dry separation methods. Report of investigations}, author = {Abel, W T and Zulkoski, M and Brady, G A and Eckerd, J W}, abstractNote = {Sulfur dioxide emissions from coal-burning power plants can be significantly lowered by removing pyrite from the coal prior to buming. . Conventional …

Pyrite – WGNHS – UW–Madison

Pyrite is the most common sulfide found in many environments. It is a common accessory mineral in igneous, sedimentary and metamorphic rocks. It also is abundant in most hydrothermal deposits. Only the most significant occurrences of pyrite in the state will be recorded here. ASHLAND COUNTY: Pyrite is a common accessory mineral in the Bad …

The approach of biodesulfurization for clean coal technologies: a

Pyrite is the predominant inorganic sulfur compound in coal in general, but there are rarely other sulfide minerals such as marcasite, millerite and pyrrhotite in coal. Apart from these, there are also sulfatic sulfur and elemental sulfur in trace amounts.

MRHS

Mill Rejects from coal mill will drop into the Pyrite Hopper through the grid. Oversize material will be retained on the grid. A pneumatic cylinder operated Plate Valve on oversize material discharge chute will be provided, which will be operated automatically in case of accumulation of oversized rejects.

Experimental Study on the Oxidation Reaction of Coal-Pyrite and …

As one of the crucial factors contributing to coal spontaneous combustion, the oxidation of pyrite is a complex process involving multiple reactions, particularly in the presence of oxidants (Fe3+ and O2) and bacteria. However, experimental results based on mineral-pyrite are not entirely applicable to coal-pyrite due to their differences in …

Thermal phase transition of pyrite from coal | SpringerLink

The thermal phase transition of pyrite from coal was studied using thermogravimetry and derivative thermogravimetric, infrared spectroscopy and X-ray …

Thermal phase transition of pyrite from coal | SpringerLink

The thermal phase transition of pyrite from coal was studied using thermogravimetry and derivative thermogravimetric, infrared spectroscopy and X-ray diffraction (XRD). According to the XRD results, the phase transition of the pyrite starts at 350 °C, pyrrhotite and magnetite are intermediate products of the oxidation from pyrite …

Pyrite oxidation: a state-of-the-art assessment of the reaction

The best explanation for this observation available at this time was provided by Caruccio (1975), who pointed out that the one factor that seems to most affect the acid production rates for coal mine wastes is the size of the pyrite grains. Laboratory measurements have consistently shown that the oxidation rate is directly proportional to …

Advances in depressants used for pyrite flotation separation …

netic values of coal pyrite and ore pyrite reached the maxi-mum at 500 °C and 550 °C, respectively. In other words, ore pyrite required a higher temperature to achieve stronger magnetic properties compared to coal pyrite. In addition, coal pyrite had a lower pyrolysis temperature and greater maximum weight loss than those of ore pyrite ...

(PDF) Occurrence Characteristics of Fine-Grained Pyrite in Coal …

Fine-grained pyrite mainly occurs in the form of framboïdal pyrite, disseminated pyrite, and monomer pyrite with a size of 0.69-33.94 μm in the middlings and cleaned coal.

Determination of the influence of pyrite on coal spontaneous …

In order to uncover the effect of pyrite on the tendency of coal to spontaneously combust, thermal analysis was carried out to characterize the reaction process of coal with different pyrite contents at four heating rates of 5, 10, 15, and 20 K min −1 in air flow from 25 to 900 °C. The Flynn-Wall-Ozawa method was applied to calculate …

In situ study of the decomposition of pyrite in coal during

The results suggest that the inherent hydrogen and oxygen in coal can promote the decomposition of pyrite at low temperature, while external H 2 plays a …

Arsenic in Coal

A, Pyrite from a bituminous coal sampled in Cullman County, Alabama. Arsenic concentration at the points shown ranges from less than the detection limit (0.01 weight percent) to 2.6 weight percent. Image by Allan Kolker, USGS. B, Pyrite collected from a fracture in bituminous coal from Walker County, Alabama.

Study of pyrite transformation during coal samples heated in CO2

Pyrite transformation in two coals heated in CO 2 was investigated. It was found that the pyrite experienced two visibility DTG peaks at temperature above 840 °C in CO 2.It may be due to the pyrite decomposed products further reacting with CO 2 to form iron oxides, sulfur oxide and CO as temperature increased. There are two main parts …

Oxidation of pyrite in coal to magnetite

When bituminous coal is heated in an inert atmosphere (He) containing small amounts of oxygen at 393–455 °C, pyrite (FeS 2) in coal is partially converted to magnetite (Fe 3 0 4).The maximum amount of Fe 3 0 4 formed during the time of heating corresponds to 5–20% of the total pyrite present, depending on the coal sample. The magnetite …

Occurrence Characteristics of Fine-Grained Pyrite in …

The pyrite in coal mostly coexists with the coal matrix, called coal-pyrite in this study, and some monomer pyrite. Among them, framboïdal pyrite, smaller euhedral …